Studies on Chemical Carcinogens. I. Reduction of 4-Substituted Quinoline N-Oxide with Sodium Borohydride
نویسندگان
چکیده
منابع مشابه
The reduction of cozymase by sodium borohydride.
Cozymase (diphosphopyridine nucleotide, DPN) has been assayed by a variety of biochemical and chemical methods (1). Among the simplest procedures has been the determination of the light absorption of reduced DPN at 340 rnp after reduction by sodium hydrosulfite. Since special precautions are required to remove completely the excess reducing agent which absorbs in this region, it appeared advant...
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Iron oxide (Fe2O3) nanoparticles were synthesized by a simple approach using sodium borohydride (NaBH4) and Iron chloride hexahydrate (FeCl3.6H2O). Their physicochemical properties were characterized by high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron dispersive spectroscopy (EDS). XRD pattern showed that the iron...
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Iron oxide (Fe2O3) nanoparticles were synthesized by a simple approach using sodium borohydride (NaBH4) and Iron chloride hexahydrate (FeCl3.6H2O). Their physicochemical properties were characterized by high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron dispersive spectroscopy (EDS). XRD pattern showed that the iron...
متن کاملSystematic investigations on the reduction of 4-aryl-4-oxoesters to 1-aryl-1,4-butanediols with methanolic sodium borohydride
4-Aryl-4-oxoesters undergo facile reduction of both the keto and the ester groups with methanolic NaBH₄ at room temperature to yield the corresponding 1-aryl-1,4-butanediols whereas 4-alkyl-4-oxoesters furnish the corresponding 1,4-butanolides via selective reduction of the keto moiety. Results of a detailed and systematic investigation of the reaction are described.
متن کاملATTEMPTED PREPARATION OF N-SUBSTITUTED DIPHENYLCYCLOPROPENEIMINE N-OXIDE
The reaction of diphenylcyclopropenone with several N-substituted hydroxylamine and primary amines are investigated. Most of these reactions led to ring opened or ring enlarged products, instead of the desired N-Oxide or imine. The reaction of cyclopropeneimine with peracid-another possible route to N-substituted cyclopropeneimine N-Oxide is studied. Most of the unexpected products are ide...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1965
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.13.1103